What about the 63/37 solder? I have some of it but can't recall being able to tell any difference when I used it.
Same here. Probably doesent matter. I just stick to what I know. 60/40 (non chinese) branded stuff like kester or multicore.
I keep 1.2mm and 0.7mm diameter depending on job. And MAGNIFYING prescription glasses! And a big block of Bluetack (2 in fact) to hold stuff for me, not enough hands.
With decent flux and cleaned (or brand new solder pads) on a board, you can use a biggish heat retaining tip, thats bigger than the pads to get perfect solder blobs across all of the solder pads at once that is well defined. Not enough flux or crap solder/flux or non tinned iron and you get bridging, flux burned off, oxidised pads. Not pre cleaned with abrasive or a fibre pen and you can get the "it wont tin" and gone all black thing happening! (Like my freind was also getting because of cheap non tinned, too hot iron...)
I use to have a cheap non thermostatic iron that was just 15 watts. It would glow orange if left plugged in. WAY too hot. Impossible to tin. And it had little thermal mass, no power so it went too cold when you touch it to a terminal or a copper trace...
I now just use a Hakko for the last 15 years. This model FX-888D is now recently discontinued. I would buy it again... Its only 70W but its temp control is fast! If it cools a degree or two in contact with work it rapidly responds. It aso does not get hotter than you set and so doesent oxidise fast.
But theres plenty of decent cheaper alternatives today. I like the weight of the holder/cleaner too. And the un-meltable ultra flexible silicone cable, and the multitude of different tips that are cheap on amazon!