by Burgerman » 27 Nov 2014, 14:43
You don't often get a "bad" cell. Of course it depends on your definition.
You can make them bad fast!
1. Discharge too low. At 2.7v there's no useful power left. Maybe a few yards... No point going lower. They drop fast right at the end. 2.5V is very low and as low as you should ever allow them to go at a push. 2.0v is really, really low! They may not recover fully and will go "bad" instantly.
2. Charge too high voltage. 3.60Volts MAX if you want a long service life and say 2k to 5k cycles. 3.65v means a considerably shorter lifespan, but easier to balance as this is well above the natural "full" state. (So they naturally want to drop down, allowing you to push more power in - making low cells to catch up as you charge. 3.70v and they don't much like it one bit. Almost every battery BMS setup repeatedly allows them to exceed 3.8v and often considerably more over and over in cyclic fashion for many hours... So avoid BMS like the plague.
3. High C rate discharge. If you take 1C from a 10C continuous cell, it will last pretty much forever. Take 5C from a 10C cell and it really wont... Take 10C from a 10C cell, and it may last a few hundred cycles at very best, usually much less. So you want HIGH C rate cells, and low C discharge rates if you want to get a lot of cycles from your pack. For this reason Headway (10C) are preferred to Thundersky, Calb, Winston etc Prismatic cells in a powerchair. We use small batteries due to space. We may need up to 240A from a pack with a powerful control system such as R-net 120.
What does bad mean? Higher resistance or low capacity, hard to balance or a bit of all three etc.
All lithium ion phosphate cells seem to live a very long life if you don't:
Go over3.60v
Go below 2.70v
DO keep as far away from the max C rate as possible.
So fit big capacity, high C rate packs, charge via a proper charge system (not a BMS!) and don't run them flat!